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ICL Phosphate Specialty - HALOX® Company Logo
HALOX® 430 JM is a non-toxic, heavy metal-free anti-corrosive pigment designed for use in waterborne and solventborne protective coating systems. HALOX® 430 JM is based on a unique synergy between an ion scavenging and passivation mechanism. It is recommended for use in long-term applications where the use of heavy metals, such as zinc, strontium, barium, molybdenum, and chromate, is of concern.

Functions: Adhesion Promoter, Corrosion Inhibitor, Coupling Agent, Pigment

Chemical Family: Calcium Phosphates, Calcium Salts

End Uses: 2K (2 component) Coating, Clearcoat, Coil Coating, Epoxy Coating, Latex, Powder Coating, Solventborne Coating, Solventless & High Solids Coating, Waterborne Coating

Pigment Type: Inorganic Pigments

Compatible Polymers & Resins: Epoxies (EP), Polyurethanes (PU)

Labeling Claims: Heavy Metal-free, Non-Toxic, Zinc-free

Features: Corrosion Resistance, Excellent Dispersibility, High Gloss, Longer Performance Life

Technical Data Sheet
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Identification & Functionality

Pigment Type
Chemical Description

Calcium Phosphate Based Inhibitor

Mechanism
Cathodic passivation and ion exchange/scavenging

Features & Benefits

Benefits

The jet-milled feature of HALOX® 430 JM offers significant advantages :

  • Thin film applications (<10 microns)
  • Easier to disperse
  • Cleaner grinds
  • Improved efficiency
The Sustainable Future
  • Patented Calcium Phosphate
  • Ion Exchange Technology
  • JM (jet milled version) for smaller particle size
Advantages
The jet-milled feature offers significant advantages for thin film applications (<10 microns). It is easy to disperse and provides cleaner grinds for improved corrosion inhibition efficiency. It is a moderate solubility corrosion inhibitor and hexavalent chromate replacement option for galvanized, Galvalume™, and aluminum alloys.

Applications & Uses

Compatible Polymers & Resins
Compatible Substrates & Surfaces
Applications
  • Thin Film Coatings
  • WB 2K Epoxies
  • SB 2K Epoxies
  • Hybrids
  • High Solids Epoxies
  • Aerospace, Auto Refinish
  • Cathodic Inhibitor
  • Clear Coats
  • Latex Emulsions
  • WB 2K Polyurethane
  • DTM Finishes
  • Polyesters
  • Powder Coatings
Recommended Loading Levels

Application recommended loading levels based on total formula weight.

Coatings System Water-borne Solvent-borne
2K Epoxy 2-6% 8-12%
Alkyds & Modified Alkyds 2-6% 6-10%
2K Polyurethane 2-6% 6-10%
Acrylic Copolymer 2-5% -
Polyester Melamine/TGIC - 6-9%

Properties

Appearance
White Powder
Typical Properties
ValueUnitsTest Method / Conditions
Density2.7g/ml-
Hegman Grindmin. 6
Mean Particle Size2microns-
Moisture Content1.1%-
Oil Absorption50lbs/100 lbs-
pH (10% Solution by Weight)8--
Solubility in Water0.02%-

Regulatory & Compliance

Certifications & Compliance

Technical Details & Test Data

HALOX® 430 JM versus Zinc Containing Cl, SZP 395

Water based Light Industrial PU DTM with 2% CI on TFW

Panel Data

B1000 Gloss Scribe Creep ASTM D
1654
ID Cross
Hatch
Adhesion
20° 60° 85° Scribe Creep
(mm)
AVG of 2
panels
B1000
% Improvement
vs CTL
            AVG of 2 panels
Blank 3B 37.4 76.2 96.4 10 CTL
2% SZP395 3B 29.5 72.6 95.6 11.75 85%
2% 430 4B 28.2 71.4 96.7 5.5 182%

ASTM B117, 144 hours, DFT @50 microns, B1000

HALOX® 430 JM - Halox® 430 Jm Versus Zinc Containing Cl, Szp 395

 

Water based Light Industrial PU DTM with 2 4% CI on TFW

Panel Data

CRS Gloss 144 hours
ID Cross
Hatch
Adhesion
20° 60° 85° Scribe Creep
(mm)
AVG of 2
panels
%
Improvement
vs CTL
            AVG of 2 panels
Blank 0B 39 76 95.7 19.75 --
2% 395 0B 30.3 72.3 97 19 104%
2%
430JM
2B 27.9 70.2 96.4 11.5 172%
4%
430JM
2B 22 66.7 95.3 9.875 200%

ASTM B117, 144 hours, DFT @50 microns, CRS

HALOX® 430 JM - Halox® 430 Jm Versus Zinc Containing Cl, Szp 395 - 1

 

Heavy Metal Free versus Zinc

Water based Light Industrial DTM Epoxy, ASTM B117, 4 mils DFT over CRS

CRS     168 Hours  
Sample Panel # DFT Visual
Scribe
Creep
Rating
ASTM
D 1654
Field
Corrosion
ASTM
D
610
Field
Blistering
ASTM D
714
Scribe Creep
(mm) AVG of
2 panels
%
Improvement
vs CTL
CW314 1 4.72 8 10 10 2.875 917%
2 4.70 8 10 10    
SZP395 1 4.56 8 10 10 3.9375 670%
2 4.55 6 10 10    
700 1 4.59 5 10 10 670% 414%
2 4.7 4 10 10    

5% loading level

HALOX® 430 JM - Heavy Metal Free Versus Zinc

 

 

Factors to Consider while Creating Coatings Solutions
  • Combine the inhibitors utilize synergy of multiple mechanisms to achieve desired performance.
    • Inorganic/Flash Rust
    • Inorganic/Inorganic
    • Inorganic/Organic
  • Optimize Solubility of the inhibitor. Synergize short term and long term corrosion inhibitors based on their solubility.
  • Inhibitor Concentration avoid direct weight to weight replacements. Beneficial to optimize usage level.
  • Substrate specific corrosion inhibitor selection can be substrate dependent.

Storage & Handling

Shelf Life
36 Months